66190 - Physical Chemistry of the Solid State M

Academic Year 2012/2013

  • Docente: Aldo Brillante
  • Credits: 4
  • SSD: CHIM/02
  • Language: Italian
  • Teaching Mode: Traditional lectures
  • Campus: Bologna
  • Corso: Second cycle degree programme (LM) in Industrial Chemistry (cod. 0884)

Learning outcomes

The course provides an introductory overview to the physical chemistry of the solid state, with particular emphasis to the structural and dynamical properties of the crystal lattice. Some methods for materials characterization will be illustrated.

Course contents

Synthesis and preparation of materials.

Crystal structure. Periodic arrays of atoms. Fundamental types of lattices. Order, periodicity, dimensionality.

Reciprocal lattice. Diffraction of waves in crystals.

Waves in periodic structures: Bloch theorem.

Crystal binding. Crystals of inert gases, ionic crystals, covalent crystals, metals, hydrogen bonds.

Optical properties. Collective excitations in solids.

Excitons: electronic spectra of molecular crystals.

Phonons: ir and Raman spectra of crystals.

Optical spectroscopy techniques in Materials Science.

Reflection Spectroscopy.

Experiments on the application of Raman spectroscopy: Raman piezospectroscopy, Polymorphism, Polarized Raman spectra and Raman mapping of organic semiconductors.

Readings/Bibliography

C. Kittel, Introduction to Solid StatePhysics, John Wiley & Sons, Inc.

G. Turell, Infrared and Raman Spectra of Crystals, Academic Press

Lecture notes

Teaching methods

Lectures in classroom and experiments in the spectroscopy laboratory

Assessment methods

Oral examination

Teaching tools

Digital projector, pc, spectroscopy lab

Office hours

See the website of Aldo Brillante