67066 - Chemistry of Organic Materials

Academic Year 2012/2013

  • Docente: Luca Bernardi
  • Credits: 6
  • SSD: CHIM/06
  • Language: Italian
  • Teaching Mode: Traditional lectures
  • Campus: Ravenna
  • Corso: First cycle degree programme (L) in Chemistry and Technologies for the Environment and Materials (cod. 8515)

Learning outcomes

The aim of the course is to give students a complete overview on the main classes of organic materials, with particular relevance to their preparation, their properties and to their applications. Competences will be acquired also in the field of biomaterials(proteins, carbohydrates, etc.). In particular, students will be able to understand the connections between the chemical structure and the technological peculiarities of the most important organic materials (dyes and pigments, luminescent and chromogenic materials, liquid crystals, ) and to evaluate the possible applications.

Course contents

Carbohydrates and cellulosic fibers:

The classification of carbohydrates

Fisher projections

Glycosides's formation

Disaccarides and polysacacrides

Cellulose, starch and glycogen.

alfa-Aminoacids, Proteins and proteic fibres

The structure of amino acids

The isoelectric point

Peptides and proteins

Classification of proteins

The proteic fibers

Organic Dyes and Pigments:

Historical Perspectives.

Physical and Chemical Basis of Colour

Azo Dyes and Pigments.

Carbonyl Dyes and Pigments

Phthalocyanines. Mode of applications.

Miscellaneous Chemical Classes of Organic Dyes and Pigments

Textile Dyes: Protein-, Cellulosic- and Synthetic-Fibres

Reactive Dyes for Textile Fibres.

Pigments, High Performance Organic Pigments

Colour and Environment. Production of dyes. Toxicology. Food Colors.

Chromogenic Materials

Definitions and Synthesis

Thermochromic Materials. Liquid Chrystals and LCD technology.

Piezochromic Materials

Electrochromic Materials

Photochromic Materials

Luminescent Materials

Nature and Origin of Luminescence. Chemi-, Bio-, and Electro-luminescence. Photoluminescence: Fluorescence and phosphorescence

Applications of Luminescence. Chemiluminescent reactions: luminol and Cyalume lamps. Bioluminescence.

Organic Electronics:

Semiconductors for “organic transistors” (OTFTs)

Organic Light- Emitting Devices (OLEDs)

Readings/Bibliography

Functional Organic Materials-Syntheses, Strategies and Applications, edited by T. J.J. Mueller, U.H.E. Bunz, Wiley-VCH, 2007

John McMurry, Fondamenti di Chimica Organica, III ed. italiana, Ed. Zanichelli

Assessment methods

Exercises and brief oral discussion on the test.

Teaching tools

Powerpoint presentations and lecture notes

Theoric lessons.

Office hours

See the website of Luca Bernardi