Foto del docente

Silvia Bordoni

Associate Professor

Department of Industrial Chemistry "Toso Montanari"

Academic discipline: CHIM/03 General and Inorganic Chemistry

Publications

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Publications prior to 2004

 

1)      L.Busetto S.Bordoni V.Zanotti

   Further reactions of [(µ-C5H5)(CO)2FeC(S)SMLn](MLn=Fe(µ-C5H5)(CO)2,Re(CO)5 with organic electrophiles

   J.Organomet.Chem.(1988), 339 , 125

 

2)      L.Busetto S.Bordoni V.Zanotti V.G.Albano D.Braga

   Synthesis and characterization of Dinuclear Iron Complexes containing bridging C(CN)SR carbene ligands. X ray structure of Fe2(CO)2(cp)2 (µ-CO)[µ-C(CN)SMe]

   Gazzetta Chimica Italiana(1988),118,667

 

3)      L.Busetto,S.Bordoni,V.Zanotti,V.G.Albano,D.Braga

   Cyanocarbene dinuclear derivatives of Iron

   "Advances in Metal  Carbene Chemistry"

   NATO ASI Series  Vol. 269 Kluwer Academic Publishers redatto dal Prof.U.Schubert (1988)

 

4)      F.Cecconi C.Ghilardi S.Midollini A.Orlandini P.Zanello B.T.Heaton L.Huang J.A.Iggo S.Bordoni

   The reactivity of the metal-metal bond in the dimer [(CH3C(CH2PPh2)3)2Rh2(µ-CO)(CH3)2CO. Synthesis and X ray structure of a paramagnetic dinuclear rhodium complex.

   J.Organomet.Chem.(1988), 353,C5

 

5)      S.Bordoni B.T.Heaton C.Seregni L.Strona R.Goodfellow M.B.Hurthouse    M.Thornton-Pett S.Martinengo

   Derivatives of [Rh6(CO)13C]2-:Solution Structure of [Rh6H(CO)13C]- from Nuclear Magnetic Resonance Measurements and X-Ray Crystal Structure of         [Rh6(CO)11C(µ-Ph2PCH2CH2PPh2)]2-

   J.Chem.Soc.Dalton Trans. (1988), 2103

 

6)      C.Allevi S.Bordoni C.P.Cleavering B.T.Heaton J.A.Iggo C. Seregni  L.Garlaschelli

   Multinuclear Magnetic Resonance Studies on Substituted   Rhodium Carbonyl Clusters

   Organometallics(1989),8,385

 

7)      S.Bordoni L.Busetto V.Zanotti

   Complessi Cianocarbenici Dinucleari: Reattivita' di [cp2Fe2(CO)2(µ-CO)[µ-C(CN)SMe2]+ con Ammine.

   La Chimica e l'Industria, 90 ,(1989)

 

8)      L.Busetto S.Bordoni V.Zanotti V.A.Albano D.Braga M.Monari

   Reactions of [cp(CO)FeC(S)SC(Fp)S] [Fp=(cpFe(CO)2)] with   Group IB and  IIB metals;  X-ray molecular structure of [cp(CO)FeC(SHgBr2)SC(Fp)S]2 

   J.Organomet.Chem.389,(1990),341-350

 

9)       V.G.Albano S.Bordoni D.Braga L.Busetto A.Palazzi V.Zanotti

   Dinuclear Cyanoalkylidene Complexes of Iron

   Angew. Chemie Int.Engl.Ed.(1991), 7, 847

 

10)S. Aime, L. Cordero, R. Gobetto, S.Bordoni, L. Busetto, V. Zanotti, V. A.  Albano, D. Braga, F. Grepioni,

   Synthesis,Molecular Structure,CrystalPacking, and Dynamic Behaviour in the Solid   State of Fe2(Cp)2(-CO)(CO)2{-CR(CN)} (R= H or CN)

   J. Chem. Soc. Dalton Trans.(1992) 2961

 

11)L.Busetto, V. Zanotti, S. Bordoni, L. Carlucci, V. A. Albano, D. Braga

   A unique example of an Octahedral Iron(II) Complex containing Four Triflate Anions and Two Nitrile-like Organometallic Cations,

   J. Chem. Soc. Dalton Trans. (1992) 1105

 

12)L. Busetto, S. Bordoni V. Zanotti, V. G. Albano, D. Braga

   Synthesis of the triiron Cyanocarbyne Fe3(Cp)3(-CO)3( 3-CCN) and X-ray  molecular structure of the permetalated acetonitrile Fe3(Cp)3(-CO)3[( 3-  CCNW(CO)5]

   New J. Chem.(1992) 16 693

 

13)S. Bordoni, F. Cavani, F. Trifiro'

   Solid State Chemistry and Catalysis: the rutile structure.

   La chimica e L' industria (1992) 3 194/.

 

14)L.Busetto, V. Zanotti, S. Bordoni, L. Carlucci, A. Palazzi

   Carbyne to Carbene ligand Conversion in dinuclear Complexes

   "Transition Metal Carbyne Complexes" (1993) 137-147

   NATO ASI Series vol. 392. Ed.F. R. Kreissl Kluwer Academic Publishers

 

15)L. Busetto, V. Zanotti, S. Bordoni, L. Carlucci A. Palazzi

   Fisher type Carbene Ligands in Dinuclear Complexes

   J. of Cluster Science(1993) 4 9

 

16)L.Busetto S.Bordoni V.Zanotti M.C.Cassani

   Further applications of the NCO- insertion into a C-SR bond: synthesis of the bis(-acylisocyanide) complex [Fe2(CO)2(Cp)2(-CNC(O)SMe)2]

   J. Organomet. Chem. (1993) 451 107

 

17)S. Bordoni, F. Castellani, F. Cavani, F. Trifiro', M. P. Kulkarni

Dispersion af V4+ ions in a SnO2 rutile matrix as a tool for the creation of active sites in ethane oxodehydrogenation

"New Developments in Selective Oxidation" Elsevier ed. (1994) 93.

 

18)S. BordoniF. Castellani F. Cavani  F. Trifiro' M. Gazzano

Nature of vanadium species in SnO2-V2O5-based Catalysts

J.Chem. Soc. Perkin Trans.(1994)  19 1981-2000

 

19)S. Bordoni, L. Busetto, M:C. Cassani, V. G: Albano, P. Sabatino

Reactions of Au(C6F5)(SC4H8) whith Diazoalkanes. Synthesis and Molecular Structure of Au(C6F5)[(C6H5)2C=N-N=C(C6H5)2].

Inorg. Chim. Acta (1994) 222 267.

 

20)S. Bordoni F. Mazza, V. Zanotti

Synthesis and reactions of the novel sulfonium-methylidene complex [Fe2(CO)2(Cp)2(-CO)-C(H)Sme 2]SO3CF3

Inorg. Chim. Acta (1994) 223 31.

 

21)S. Bordoni L. Busetto M. C. Cassani V. Zanotti V. G.Albano M. Monari F. Prestopino e P. Sabatino

Diiron  thiocarbyne complexes: chemistry of [Fe2(-CNC(O)SMe)(-CSMe)(CO)2Cp2]SO3CF3 and molecular structure of the trans isomer

Gazz. Chim: Ital. (1995) 125 57.

 

22)S.Bordoni L. Busetto F. Calderoni L. Carlucci F. Laschi P. Zanello V. Zanotti

Redox Chemistry and substitution reactions of the m-cyanoalkylidene complexes [Fe2(CO)2(Cp)2(m-CO){ m-C(CN)(X)}] n+  (n=0, X=CN,H,Me,SMe,OMe,OEt,OPh,OCH2CH=CH2,PEt2, or NC5H10; n=1, X=PMe2Ph)

J.Organomet.Chem.(1995) 496 27

 

23)V.Zanotti S.Bordoni L.Busetto L.Carlucci A.Palazzi R.Serra V.G. Albano M. Monari F. Prestopino F. Laschi P. Zanello

Diiron Aminoalkylidene Complexes

Organometallics (1995) 14 5232

 

24)V.G. Albano S.Bordoni L.Busetto M.Monari V.Zanotti

An unusual Hydrogen Migration from a cyclopentadienyl to a m-Carbyne Carbon in the reaction of Grignard Reagents with [Fe2(CO)2(Cp)2(m-CO){ m-CSMe]SO 3CF3

Organometallics (1995) 14 5455

 

25)V.G.Albano S.Bordoni L.Busetto C.Camilletti M.Monari F.Prestopino V.Zanotti

A new route to diiron bis-m-thiocarbene complexes: molecular structure of [Fe{m-C(CN)SMe}(Cp)] 2(Cp=h-C 5H5) containing the unusually folded six-membered metallacycle Fe2C2S2

 J. Chem.Soc. Dalton Trans. (1996) 3693

 

26)F. Azzaroni P. Biscarini S. Bordoni G. Longoni E. Venturini

Catalytic hydroformilation of (1S,5S)-(-)- and (1R,5R)-(+)- Pinene: stereoselective Synthesis and Spectroscopic Characterization of (1S, 2R,5R)-(1R,2R,5R)-and (1R,2S,5R)-10 formilpinane.

 J. Organomet. Chem. (1996) 508 59.

 

27)S. Bordoni L. Busetto P. Colucci A. Palazzi V. Zanotti

Synthesis and spectrosopic properties of hetero-polynuclear cyano-bridged complexes

J. Organomet. Chem. (1997) 545 117

 

28)V. G. Albano S. Bordoni L. Busetto C. Camilletti M. Monari A. Palazzi F. Prestopino V. Zanotti

Carbon-Carbon bond formation in the reactions of diiron m-carbyne complexes with 2-thienyllithium, synthesis and structural characterization

J. Chem. Soc. Dalton Trans(1997) 4665

 

29)S. Bordoni L. Busetto C. Camilletti V. Zanotti V.G. Albano M. Monari F Prestopino

Selective formation of one or two C-C bonds promoted by carbanion addition to [Fe2(m-CSMe)(m-CO)(CO) 2Cp2]SO3CF3

Organometallics(1997) 1224

 

30)S. Bordoni L. Busetto M.C. Cassani A. Palazzi V. Zanotti

            The m-solfonium-methylidene diiron complexes [Fe2(m-C(X)SMe 2)(m-CO)(CO) 2Cp2]SO3CF3 (X=CN,H) as precursors of the mu-alkylidene compexes

Inorg. Chimica Acta (1999) 291 333

 

31) V. G Albano; S. Bordoni;L. Busetto; A. Palazzi; P. Sabatino;V.  Zanotti, .  Dithiocarbamate derivatives of m-thiocarbyne complexes: synthesis and X-ray molecular structure of [Fe2(m-CS)(m-CSMe)(m-S2CNMe2)Cp2].  

 Journal of Organometallic Chemistry  (2002),  659(1-2),  15-21.

 

32) A. Palazzi; S. Stagni; S.Bordoni; M. Monari;S. Simona. 

Interannular Conjugation in New Iron(II) 5-Aryl Tetrazolate Complexes.    Organometallics  (2002),  21(18),  3774-3781.

 

33) Albano V. G.; S. Bordoni; L. Busetto; F. Marchetti; M. Monari; V. Zanotti.

 C-N coupling between m-aminocarbyne and nitrile ligands promoted by tolylacetylide addition to [Fe2{m-CN(Me)(Xyl)}(m-CO)(CO)(NCCMe3)(Cp)2][SO3CF3]. Formation of a novel bridging h1:h2 allene-diaminocarbene ligand.    Journal of Organometallic Chemistry  (2003),  684(1-2),  37-43.

 

34) A. Palazzi; P. Sabatino; S. Stagni; S. Bordoni; V.G. Albano; C. Castellari.  Coordinating properties of [M(CO)5(CN)]- [M = Cr; Mo; W] ligands: formation of ion pairs or dinuclear cyanide-bridged complexes, spectroscopic and x-ray diffraction studies.    Journal of Organometallic Chemistry  (2004),  689(14),  2324-2337.