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Maria Cristina Cassani

Associate Professor

Department of Industrial Chemistry "Toso Montanari"

Academic discipline: CHIM/03 General and Inorganic Chemistry

Publications

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Publications prior to 2004

Pubblicazioni

1."Reactions of [Fe2{ m-C(CN)SMe2}( m-CO)(CO)2(Cp)2]SO3CF3 (Cp = h-C5H5) with alcohols", L. Busetto, M.C. Cassani, V. Zanotti, V.G. Albano, and D. Braga J.Organomet.Chem., 415, 1991, 395-405.

2."Further applications of the NCO- insertion into a C-SR bond: synthesis of the bis( m-acylisocyanide) complex [Fe2(CO)2(Cp)2{ m-CNC(O)SMe}2}ÃÆ'¢â‚¬, L. Busetto, S. Bordoni, V. Zanotti and M.C. Cassani J.Organomet.Chem., 451, 1993, 107-110.

3. "Procedure for the producing of vanadium bis-arenes from vanadium oxychloride", F. Calderazzo, G. Pampaloni, F. Masi, A. Moalli, M.C. Cassani, R. Invernizzi; (ECP Enichem Polimeri S.r.l.) Eur.Pat.Appl. E.P. 0525857 (Cl. C07F9/00), 03 Feb. 1993; IT Appl. 91/MI1934, 12 Jul.1991.

4. "Reactions of [Au(C6F5)(SC4H8) ] with Diazoalkanes. Synthesis and Molecular Structures of [Au(C6F5)(Ph2C=N-N=CPh2)]ÃÆ'¢â‚¬, S. Bordoni, L. Busetto, M.C. Cassani, V.G. Albano and P. Sabatino Inorg.Chim.Acta, 222, 1994, 267-273.

5. "Diiron thiocarbyne complexes: chemistry of [Fe2 { m-CNC(O)SMe }( m-CSMe)(CO)2(Cp)2 ] [SO3CF3 ] and molecular structure of the trans isomer", L. Busetto, S. Bordoni, M.C. Cassani, V. Zanotti, V.G. Albano, M. Monari, F. Prestopino and P. Sabatino Gazzetta Chimica Italiana, 125, 1995, 57-62.

6. "Synthesis of dinuclear Iron and Ruthenium aminoalkylidene complexes and molecular structure of the novel cis- [Ru2(CO)2(Cp)2 { m-(CN)N(Me)Bz } 2 ] (Cp= h-C5H5; Bz=CH2Ph)", V.G. Albano, L. Busetto, L. Carlucci, M.C. Cassani, M. Monari, V. Zanotti J.Organomet.Chem., 488, 1995, 133-139.

7. "Synthesis of new heterodinuclear aminocarbyne complexes: X-ray structures of [AuW{ m-CN(Et)Me}(C6F5)(CO)2(Cp)] and [CuW{ m-CN(Et)Me}(CO)2(Cp)Cl]2", V.G. Albano, L. Busetto, M.C. Cassani, P. Sabatino, A. Schmitz, V. Zanotti J.Chem.Soc., Dalton Trans., 1995, 2087-2093.

8. "The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K([18]crown-6) ] [Ln{ h 5-C5H3(SiMe3)2-1,3}2(C6H6) ] (Ln = La or Ce)", M.C. Cassani, Y.K. Gun'ko, P.B. Hitchcock and M.F. Lappert Chem.Commun., 1996, 1987-1988.

9. "Mass spectrometric detection of reactive intermediates. The reaction mechanism of diazoalkanes with Pt(0) and Gold(I) complexes", R. Bertani, R. Michelin, M. Mozzon, P. Traldi, R. Seraglia, L. Busetto, M.C. Cassani, P. Tagliatesta, G. D'Arcangelo Organometallics, 16, 1997, 3229-3233.

10. "The first identification by their EPR spectra of La2+ organometallic intermediates (and EÃÆ'‚½ for La3+ ÃÆ'‚® La2+) in the CO activation of dimethoxyethane", M.C. Cassani, M.F. Lappert, F. Laschi Chem. Commun., 1997, 1563-1564.

11.  "Magnetic resonance spectroscopic studies of a tetraaryl-distannene and -digermene [M2R4 ] (R = C6HBut-2-Me3-4,5,6 and M = Sn or Ge)", M.A. Della Bona, M.C. Cassani, J.M. Keates, G.A Lawless, M.F. Lappert, M. StÃÆ'Æ'¼rmann, M. Weidenbruch J. Chem. Soc., Dalton Trans., 1998, 1187-1190.

12. "The first example of a crystalline subvalent organolanthanum complex: [K( [18 ]crown-6)( h 2-C6H6)2] [(LaCptt2) 2( m- h 6: h 6-C6H6) ]2C6H6, notable also for having a bridging benzene radical anion ligand", M.C. Cassani, D.J. Duncalf, Michael F. Lappert J.Am.Chem.Soc., 120, 1998, 12958-12959.

13. "The m-sulfonium-methylidene diiron complexes [Fe2{ m-C(X)SMe2}( m-CO)(CO)2(Cp) 2]SO3CF3 (X = CN, H) as precursors of m-alkylidene complexes", S. Bordoni, L. Busetto, M.C. Cassani, A. Palazzi and V. Zanotti Inorganica Chimica Acta, 291, 1999, 333-340.

14. "Synthesis and Characterization of Organolanthanidocene(III) (Ln La, Ce, Pr, Nd) complexes containing the 1,4-Cyclohexa-2,5-dienyl ligand (benzene 1,4 dianion); structures of [K([18]crown-6) ] [Ln{ h 5-C5H3(SiMe3)2-1,3}2(C6H6) ] [CpÃÆ'¢â‚¬ = h 5-C5H3(SiMe3)2-1,3; Ln = La, Ce or Nd]", M.C. Cassani, Y. K. Gun'ko, P. H. Hitchcock, M. F. Lappert, F. Laschi Organometallics, 18, 1999, 5539-5547.

15.  "Coordination Chemistry of Cyclopentadienyl-Ester-Disubstituted Ligands. Synthesis and Solid State Structures of [Na([18]-crown-6)][C5H3(CO2Et) 2-1,2] and [Mn {C5H3(CO 2Ph)2-1,2 }(CO)3]", L. Busetto, M.C. Cassani, V. Zanotti, V.G. Albano, P. Sabatino Organometallics, 20, 2001, 282-288.

16.  "Procedure for the preparation of metal complexes containing hydroxycarbonylcyclopentadienide ligands", L. Busetto, M.C. Cassani, R. Mazzoni; UniversitÃÆ'Æ'  degli Studi di Bologna, IT BO20010308, 17/05/2001. Eur. Pat. EP 1258487A1, 20/11/2002.

17. "Coordination Chemistry of Ester Functionalized Cp Ligands. The Atom-Economy Synthesis of Na[C5H4CO2(CH2)2OH] and Solid State Structures of [Rh{C5H4CO 2(CH2)2OH }(CO)2] and [Rh2{ m-(C5H4CO2CH2)2}(NBD)2]", L. Busetto, M.C. Cassani, V.G. Albano, P. Sabatino Organometallics, 21, 2002, 1849-1855.

18.  "Mini review. Aspects of non-classical organolanthanide chemistry", M.C. Cassani, Y.K. Gun'ko, P.B. Hitchcock, A.G. Hulkes, A.V. Khvostov, M.F. Lappert, A. V. Protchenko J.Organomet.Chem., 647, 2002, 71-83.

19.  "Coordination Chemistry of Ester-Functionalized Cp Ligands. A Versatile Approach to the Chiral Hydroxyalkoxycarbonylcyclopentadienide [C5H4CO2(CHMe)2OH]-. Synthesis, Structure and Catalytic Activity of Rhodium(I) and Iron(II) Complexes", L. Busetto, M.C. Cassani, R. Mazzoni, V.G. Albano, P. Sabatino, P. Frediani, E. Rivalta Organometallics, 21, 2002, 4993-4999.

20.  "Hydroformylation of olefins catalysed by alkoxycarbonylcyclopentadienyl complexes of rhodium(I)", L. Busetto, M.C. Cassani, R. Mazzoni, P. Frediani, E. Rivalta J.Mol.Catal. A: Chemical, 206, 2003, 153-161.

21. "Coordination Chemistry of Ester-Functionalized Cp Ligands. Synthesis and Catalytic Activity of [Rh {CpCO2(CHPh)2OH}(NBD)] and [Rh{CpCO2(CH2)3OH}(NBD)]", L. Busetto, M.C. Cassani, R. Mazzoni, P. Frediani and E. Rivalta J. Organomet. Chem., 689, 2004, 2216-2227.

22. "Synthesis of New Poly(propylenimine) Dendrimers DAB-dendr-[NH(O)COCH2CH 2OC(O)C 5H 4Rh(NBD)] n {n = 4, 8, 16, 32, 64} Functionalized with Alkoxycarbonylcyclopentadienyl Complexes of Rhodium(I)", L. Busetto, M.C. Cassani, P.W.N.M. Van Leeuwen, R. Mazzoni Dalton Trans., 2004, 2767-2770.

23. "One-Pot Synthesis of the New Dianionic Ligand [Na]2[C5H4CO2(CH2)2NTs]; Preparation and Structures of Two Rhodium Derivatives", L. Busetto,  M.C. Cassani, R. Mazzoni, V.G. Albano, P. Sabatino, J. Organomet. Chem., 690, 2005, 818-824.

24. "Synthesis and characterisation of a series of 1,2-phenylenedioxoborylcyclopentadienyl-metal complexes [Ti(IV), Zr(IV), Hf(IV), La(III), Ce(III), Yb(III), Sn(II) and Fe(II)]", M.C. Cassani, M.J. Davies, P.B. Hitchcock, M.F. Lappert, Inorganica Chimica Acta, Special Issue dedicated to Professor F.G.A. Stone, 358, 2005, 1595-1604.

25.  ÃÆ'¢â‚¬Å“Clean and Efficient Synthesis of Air Stable Polymer-Supported Alkoxycarbonylcyclopentadienyl Rhodium(I) ComplexesÃÆ'¢â‚¬, L. Busetto, P.L. Buldini, M.C. Cassani, Rita Mazzoni, J. Organomet. Chem. , 691, 2006, 573-578.

26. "PGSE NMR Studies on DAB-Organo-Rhodium Dendrimers: Evaluation of the Molecular Size, Self-Aggregation Tendency and Surface Metal Density", D. Zuccaccia, L. Busetto, M.C. Cassani, A. Macchioni, R. Mazzoni, Organometallics, 25, 2006, 2201-2208.

27. "Enzyme electrodes based on Sono-Gel containing ferrocenyl compounds", B. Ballarin, M.C. Cassani, R. Mazzoni, E. Sc avetta, D. Tonelli, Biosensors and Bioelectronics, 22, 2007 , 1317-1322.  

28. "Glucose Biosensor  Mediated by 1,2 Diferrocenylethane in a Sono-gel Composite Electrode", B. Ballarin, M. C. Cassani, R. Mazzoni, E. Scavetta, G. Trioschi, D. Tonelli Electroanalysis, 19, 2007, 200-206.

29. "Synthesis, molecular structures and solution NMR studies of N-heterocyclic carbene-amine  silver complexes", L. Busetto, M.C. Cassani, C. Femoni, A. Macchioni, R. Mazzoni, D. Zuccaccia, J. Organomet. Chem.  693, 2008, 579-591.

30. "Self-assembled gold nanoparticles modified ITO electrodes: The monolayer binder molecule effect", B. Barbara, M.C. Cassani, E. Scavetta, D. Tonelli,  Electrochimica Acta  53, 2008,  8034-8044. 

31. "A New Gold(III)-Aminoethyl Imidazolium Aurate Salt: Synthesis, Characterization and Reactivity", B. Ballarin, L. Busetto, M.C. Cassani, C. Femoni, Inorg. Chim. Acta , 363,  2010,  2055.

32. "Gold Nanoparticle-Containing Membranes from in Situ Reduction of a Gold(III)-Aminoethylimidazolium Aurate Salt", B. Ballarin, M.C. Cassani, D. Tonelli, E. Boanini, S. Albonetti, M. Blosi, M. Gazzano J. Phys. Chem. C, 114, 2010, 9693.

33.  "A New Gold(III)-Aminoethyl Imidazolium Aurate Salt as Precursor for Nanosized Au Electrocatalysts", B. Ballarin, M.C. Cassani, M. Gazzano, G. Solinas, Electrochim. Acta, 56, 2010, 676-686.

34. "RF-sputtering preparation of gold nanoparticles modified ITO electrodes and electrocatalytic applications", B. Ballarin, M.C. Cassani, C. Maccato, A. Gasparotto, Nanotechnology, 22, 2011, 275711.

35. "N-Heterocyclic Carbene-Amide Rhodium(I) Complexes: Structures, Dynamics, and Catalysis", L. Busetto, M. C. Cassani, C. Femoni, M. Mancinelli, A. Mazzanti, R. Mazzoni, G. Solinas, Organometallics, 30, 2011, 5258.

36. "Primary amino-functionalized N-heterocyclic carbene ligands as support for Au(I)-Au(I) interactions: structural, electrochemical, spectroscopic and computational studies of the dinuclear [Au2(NH2(CH2)2imMe)2][NO3]2", B. Ballarin, L. Busetto, M. C. Cassani, C. Femoni, A. M. Ferrari, I. Miletto, G. Caputo, Dalton, 41, 2012, 2445-2455.

37. "Tailored SiO2-based coatings for dye doped superparamagnetic nanocomposites", L. Caruana, A.L. Costa, M.C. Cassani, E. Rampazzo, L. Prodi, N. Zaccheroni, Colloids and Surfaces A: Physicochem. Eng. Aspects, 410, 2012, 111-118.

38. "Straightforward Synthesis of Gold Nanoparticles Supported on Commercial Silica-Polyethyleneimine Beads", S. Fazzini, D. Nanni, B. Ballarin, M. C. Cassani, M. Giorgetti, C. Maccato, A. Trapananti, G. Aquilanti, S. I. Ahmed, J. Phys. Chem. C, 116,  2012, 25434-25443.

39. "Homogeneous catalytic hydrogenation of perfluoro methyl esters", D. Lazzari, M. C. Cassani, M. Bertola, F. Casado Moreno, Damiano Torrente, RSC Adv., 3, 2013, 15582-15584.

40. "Fluoroalkyl allyl ethers: Useful building blocks for the synthesis of environmentally safer fluorinated multiblock molecules", D. Lazzari, M. C. Cassani,, G. Solinas, M. Pretto, J. Fluorine Chem., 156, 2013, 34-37.

41. "Simple one step electrochemical preparation of copper nanostructures", A. Mignani, B. Ballarin, E. Boanini, M. C. Cassani, Electrochim. Acta, 115, 2014, 537-545.

42. "Cationic-anionic polyelectrolyte interaction as a tool to graft silver nanoparticles on hydroxyapatite crystals and prevent cytotoxicity", E. Boanini, P. Torricelli, M. C. Cassani, G. A. Gentilomi, B. Ballarin, K. Rubini, F. Bonvicini, A. Bigi, RSC Adv., 4, 2014,  645-652.

43. "Solvent-free catalytic isomerization of perfluoroalkyl allyl ethers", M. C. Cassani, D. Lazzari, M. A. Brucka, G. Solinas, M. Pretto, New J. Chem., 38, 2014,  641-649.

44. "N-Heterocyclic Carbene Rhodium(I) Complexes Containing an Axis of Chirality: Dynamics and Catalysis", M. C. Cassani, M. A. Brucka, C. Femoni, M. Mancinelli, A. Mazzanti, R. Mazzoni, G. Solinas, New J. Chem., 38, 2014, 1768-1779.

45. "Synthesis of gold nanoparticles within silica monoliths through irradiation techniques using Au(I) and Au(III) precursors", M. Tonelli, S. Turrell, O. Cristini-Robbe, H. El Hamzaoui, B. Capoen, M. Bouazaoui, M. Gazzano, M. C. Cassani, RSC Adv., 4, 2014, 26038-26045.

46. "Homogeneous Ruthenium Catalysts for the Transformation of Perfluorinated Building Blocks", D. Lazzari, M.C. Cassani, M. Bertola, R. Rossato, LA CHIMICA E L'INDUSTRIA, 2014, 4, 45-50.

47. "Novel Synthesis of Gold Nanoparticles Supported on Alkyne-Functionalized Nanosilica", S. Fazzini, M.C. Cassani, B. Ballarin, E. Boanini, J.-S. Girardon, A.-S. Mamede, A. Mignani, D. Nanni,  J. Phys. Chem. C , 2014, 118, 24538-24547. DOI: 10.1021/jp507637m

48. "Sterically driven synthesis of ruthenium and ruthenium-silver N-heterocyclic carbene complexes", R. Mazzoni, C. Cesari, S. Conti, S. Zacchini, V. Zanotti, M.C. Cassani, Dalton Trans., 2014, 17240-17243; DOI: 10.1039/C4DT02747G, Communication.

49. "Mild fabrication of silica-silver nanocomposites as active platforms for environmental remediation", A. Mignani, S. Fazzini, B. Ballarin, E. Boanini, M. C. Cassani, C. Maccato, D. Barreca, D. Nanni, RSC Adv. 2015, 5, 9600-9606.

50.  “ Fluoroalkylsilanes with Embedded Functional Groups as Building Blocks for Environmentally Safer Self-Assembled Monolayersâ€, B. Ballarin, D. Barreca, M. C. Cassani, Giorgio Carraro, Chiara Maccato,  A. Mignani, D. Lazzari, M. Bertola, Langmuir, 2015, 31, 6988-6994.

 



 

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