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Cristina Femoni

Full Professor

Department of Industrial Chemistry "Toso Montanari"

Academic discipline: CHIM/03 General and Inorganic Chemistry

Publications

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Publications prior to 2004

1.      F. Calderoni, F. Demartin, F. Fabrizi de Biani, C. Femoni, M. C. Iapalucci, G. Longoni, P. Zanello: “Electron-Sink Behaviour of the Carbonylnickel Clusters [Ni32C6(CO)36] 6- and [Ni38C6(CO)42] 6-: Synthesis and Characterisation of the Anions [Ni32C6(CO)36] n- (n = 5-10) and [Ni38C6(CO)42] n- (n = 5-9) and Crystal Structure of [PPh3Me]6[Ni32C6(CO)36].4MeCN”, Eur. J. Inorg. Chem. 1999, 663-671. DOI: 10.1002/(SICI)1099-0682(199904)1999:4<663::AID-EJIC663.

2.      F. Fabrizi de Biani, C. Femoni, M. C. Iapalucci, G. Longoni, P. Zanello, A. Ceriotti: “Redox Behaviour of [H6-nNi38Pt6(CO)48]n- (n = 4-6) Anions: a Series of Metal Carbonyl Clusters Displaying Electron-Sink Features”, Inorg. Chem. 1999, 38, 3721-3724. DOI: 10.1021/ic9813516.

3.      F. Demartin, C. Femoni, M. C. Iapalucci, G. Longoni, P. Macchi: “New Ni-Pt Carbonyl Clusters with a Tetrahedron of Platinum Atoms Encapsulated in an Incomplete Tetrahedron of Nickel Atoms: [Ni36Pt4(CO)45]6- and [Ni37Pt4(CO)46]6-“, Angew. Chem. Int. Ed. 1999, 38, 531-533. DOI: 10.1002/(SICI)1521-3773(19990215)38:4<531::AID-ANIE531>3.0.CO;2-N.

4.      G. Longoni, C. Femoni, M. C. Iapalucci, and P. Zanello: “Electron-Sink Features of Homoleptic Transition-Metal Carbonyl Clusters”, Metal Clusters in Chemistry, P. Braunstein, L. A. Oro, P. R. Raithby Eds., Wiley-VCH, Vol.2, 1999, 1137-1158. ISBN: 978-3-527-29549-4.

5.      V. G. Albano, M. Monari, F. Demartin, P. Macchi, C. Femoni, M. C. Iapalucci, G. Longoni: “Synthesis and Chemical Behavior of [MFe4(CO)16]n- (M = Au, Zn, Cd, Hg) Clusters: X Ray Structure of [NMe3CH2Ph]2[Au{Fe2(CO) 8}2]Cl and [PPh4]2[Cd{Fe2(CO)6(μ-CO) 2}2]2CH3CN”, Solid State Sciences 1999, 1, 597-606. doi: 10.1016/S1293-2558(00)80111-9.

6.      V. G. Albano, C. Castellari, C. Femoni, M. C. Iapalucci, G. Longoni, M. Monari, M. Rauccio, S. Zacchini: “Synthesis and structural characterization of [NEt4][Fe3(μ3-O)(μ3-AuPPh3)(μ-CO)3(CO)6], the New [Au6(μ3-S)2(PPh3)6][Fe3(μ3-S)(μ-AuPPh3)(CO)9]2 and [Au6(μ3-S)2(PPh3)6][Fe5(μ3-S)2(CO)14] ionic solids containing assemblages of cluster-cations and cluster-anions”, Inorganica Chimica Acta 1999, 291, 372-379. doi: 10.1016/S0020-1693(99)00134-6.

7.      V. G. Albano, F. Demartin, C. Femoni, M. C. Iapalucci, G. Longoni, M. Monari, P. Zanello: “Synthesis and Characterization of New Paramagnetic Nickel Carbonyl Clusters Containing Antimony Atoms: X-Ray Structure of [NEt3CH2Ph]2[Ni15(μ 12-Sb)(CO)24] and [NEt4]3[Ni10Sb2(μ12-Ni)(CO) 18]”, J. Organomet. Chem. 2000, 593, 325-334. doi: 10.1016/S0022-328X(99)00523-9.

8.      C. Femoni, M. C. Iapalucci, G. Longoni, P. H. Svensson: “A High Nuclearity Ni-Sb Carbonyl Cluster Displaying Unprecedented Metal Stereochemistries: Synthesis and X-Ray Structure of [NEt4]6[Ni31Sb4(CO) 40].2Me2CO”, Chem. Comm. 2000, 8, 655-656. DOI: 10.1039/b000783h.

9.      C. Femoni, M. C. Iapalucci, G. Longoni, P. H. Svensson, J. Wolowska: “Homoleptic Carbonyl Ni-Pd Clusters: Synthesis of [Ni16Pd16(CO)40]4- and [Ni26Pd20(CO)54]6- and Structural Characterization of [NnBu4]4[Ni16Pd16(CO) 40]”, Angew. Chem. Int. Ed. 2000, 39, 1635-1637. DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1635::AID-ANIE1635>3.0.CO;2-#.

10.  C. Femoni, F. Demartin, M. C. Iapalucci, A. Lombardi, G. Longoni, C. Marin, P. Svensson: “New Ni-Rh Carbonyl Clusters with Unprecedented Structural and Electronic Features: Synthesis and X-ray Structure of [NEt4]3[Ni10Rh(CO)19].C 2H5CN, [NMe3CH2Ph]3[Ni6Rh3(CO) 17] and [NEt4]3[Ni9Rh3(CO)22]”, J. Organomet. Chem. 2000, 614, 294-303. doi: 10.1016/S0022-328X(00)00632-X.

11.  J. F. Bickley, R. P. Bonar-law, C. Femoni, E. J. MacLean, A. Steiner, S. J. Teat “Dirhodium (II) carboxylate complexes as building blocks. Molecular squares with tilted walls”, J. Chem. Soc., Dalton Trans. 2000, 4025-4027. DOI: 10.1039/b008060h.

12.  R. P. Bonar-law, T. D. McGrath, N. Singh., J. F. Bickley, C. Femoni, A. Steiner: “Dirhodium (II) carboxylate complexes as building blocks. Structures of cis-chelate complexes”, J. Chem. Soc., Dalton Trans. 2000, 4343-4347. DOI: 10.1039/b007428o.

13.  R. P. Bonar-law, J. F. Bickley, C. Femoni, A. Steiner: “Dirhodium (II) carboxylate complexes as building blocks. Macrocyclic dimers with vertically stacked Rh24+ units”, J. Chem. Soc., Dalton Trans. 2000, 4244-4246. DOI: 10.1039/b007625m.

14.  M. Hasan, I. V. Kozhevnikov, M. R. H. Siddiqui, C. Femoni, A. Steiner, N. Winterton: “N,N'-Dialkylimidazolium Chloroplatinate(II), Chloroplatinate(IV), and Chloroiridate(IV) Salts and an N-Heterocyclic Carbene Complex of Platinum(II): Synthesis in Ionic Liquids and Crystal Structures”, Inorganic Chemistry 2001, 40, 795-800. DOI: 10.1021/ic000606o.

15.  V. G. Albano, C. Castellari, C. Femoni, M. C. Iapalucci, G. Longoni, M. Monari, S. Zacchini: “Synthesis, Chemical Characterization and Molecular Structure of Au8{Fe(CO)4}4(dppe)2 and l Au6Cu2{Fe(CO)4}4(dppe) 2”, J. Cluster Sci. 2001, 12, 75-87. DOI: 10.1023/A:1016666827732.

16.  F. Demartin, F. Fabrizi de Biani, C. Femoni, M. C. Iapalucci, G. Longoni, P. Macchi, P. Zanello: “Synthesis, Electrochemistry and Crystal Structure of the [Ni36Pt4(CO)45]6- and [Ni37Pt4(CO)46]6- Hexaanions”, J. Cluster Sci. 2001, 12, 61-74. DOI: 10.1023/A:1016614810894.

17.  S. Grilli, L. Lunazzi, A. Mazzanti, D. Casarini, C. Femoni: “Conformational Studies by Dynamic NMR.78. Stereomutation of the Helical Enantiomers of Trigonal Carbon Diaryl-Substituted Compounds: Dimesitylketone, Dimesitylthioketone, and Dimesitylethylene”, Journal of Organic Chemistry 2001, 66, 488-495. DOI: 10.1021/jo001287l.

18.  R. P. Bonar-Law, T. D. McGrath, J. F. Bickley, C. Femoni, A. Steiner: “Dirhodium(II) carboxylate complexes as building blocks. Synthesis of dimeric species as connectors for macrocycles”, Inorganic Chemistry Communications 2001, 4, 16-18. doi: 10.1016/S1387-7003(00)00182-9.

19.  B. F. Bonini, C. Femoni, M. C. Franchini, M. Fochi, G. Mazzanti, A. Ricci, G. Varchi: “One Pot Sythesis of New β-Lactames Containing the Ferrocene Moiety”, Synlett. 2001, 7, 1092-1096. ISSN 0936-5214.

20.  C. Femoni, M. C. Iapalucci, G. Longoni, P. H. Svensson: “New High-Nuclearity Ni-Pt Carbonyl Clusters: Synthesis and X-ray Structure of the Ordered [Ni24Pt14(CO)44]4- and the Substitutionally Ni/Pt Disordered [Ni10(Ni6-xPtx)Pt8(CO) 30]4- (x = 1.92) Tetraanions”, Chem. Comm. 2001, 1776-1777. DOI: 10.1039/b103610f.

21.  C. Femoni, M. C. Iapalucci, G. Longoni, P. H. Svensson: “The new enneanuclear nickel carbonyl anion [Ni9(CO)16]2- and its relationship with the [Ni12(CO)21]4- and [Ni6Rh3(CO)17]3- clusters”, Inorganica Chimica Acta 2002, 330, 111-117. doi:10.1016/S0020-1693(01)00769-1.

22.  D. Collini, C. Femoni, M. C. Iapalucci, G. Longoni, P. H. Svensson, P. Zanello: “Tuning Electronic Behavior of Carbonyl Metal Clusters by Substitution of Interstitial and Capping Atoms”, Angewandte Chemie Int. Ed. 2002, 41, 3685-3688. DOI: 10.1002/1521-3773(20021004)41:19<3685::AID-ANIE3685>3.0.CO;2-7.

23.  D. Collini, C. Femoni, M. C. Iapalucci, G. Longoni, P. H. Svensson: “New bimetallic Ni-Rh Carbonyl Clusters: synthesis and X-ray structure of the trigonal antiprismatic [NiRh5(CO)14]3- and body-centered cubic [NiRh14(CO)28]4- cluster anions”, Inorganica Chimica Acta 2003, 350, 321-328. doi: 10.1016/S0020-1693(02)01545-1.

24.  L. Bernardi, V. Cere, C. Femoni, S. Pollicino, A. Ricci: “Organometallic reactions in aqueous media: Indium-promoted additions to 2-pyridyl and glyoxylic acid oxime ethers”, Journal of Organic Chemistry 2003, 68, 3348-3351. DOI: 10.1021/jo026823j.

25.  D. Collini, C. Femoni, M. C. Iapalucci, G. Longoni, P. Zanello: “Modulation of Electronic Behaviour of Metal Carbonyl Clusters”, Perspectives in Organometallic Chemistry, C. G. Screttas and B. R. Steele Eds., The Royal Society of Chemistry, Vol. 287, 2003, 183-195. DOI: 10.1039/9781847551641.

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