Foto del docente

Carla Carfagna

Professoressa associata

Dipartimento di Chimica Industriale "Toso Montanari"

Settore scientifico disciplinare: CHIM/03 CHIMICA GENERALE E INORGANICA

Pubblicazioni

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Pubblicazioni antecedenti il 2004

Pubblicazioni di Carla Carfagna

1) E. Barchiesi, S. Bradamante, C. Carfagna, R. Ferraccioli, G.A. Pagani

"Evaluation of the polar-inductive and mesomeric effects exerted on contiguous functionalities by  N-oxidopyridinium groups"

J. Chem. Soc. Perkin Trans. II 1987, 1009-1013

Impact Factor 1.77

 

2) E. Barchiesi, S. Bradamante, C. Carfagna, R. Ferraccioli

"Transmission of substituent effects through the methyleneamino group N=CH : Aldehyde phenylhydrazones and conjugate anions"

J. Chem. Soc. Perkin Trans. II 1988, 1565-1572

Impact Factor 1.77

 

3) C. Carfagna, A. Musco, R. Pontellini, G. Terzoni

"MgH2 as a reducing agent in the presence of transition metal halides. Part I. Reduction of organic halides"

J. Mol. Catal. 1989, 57, 23-28

Impact Factor 2.947

 

4) C. Carfagna, A. Musco, R. Pontellini, G. Terzoni

"MgH2 as a reducing agent. Part II. Reduction of organic halides in presence of Ni (0) and Pd (0) complexes"

J. Mol. Catal. 1989, 54, L23-L26

Impact Factor 2.947

 

5) C. Carfagna, A. Musco, G. Sallese, R. Santi, T. Fiorani

"Palladium - catalyzed coupling reactions of aryl triflates or halides with ketene trimethylsilyl acetals. A new route to alkyl 2-arylalkanoates"

J. Org. Chem. 1991, 56, 261-263

Impact Factor 4.638, Q1

 

6) C. Carfagna, L. Mariani, A. Musco, G. Sallese, R. Santi

"The Regio - and Stereoselectivities of the reaction of allyl acetates and silyl ketene acetals catalyzed by Pd (0) complexes: a new route to cyclopropane derivatives"

J. Org. Chem. 1991, 56, 3924-3927

Impact Factor 4.638, Q1

 

7) C. Carfagna, R. Galarini, A. Musco, R. Santi

"Platinacyclobutane complexes from nucleophilic attack at a coordinated allyl group and catalytic formation of cyclopropanes in the presence of platinum complexes"

Organometallics 1991, 10, 3956-3958

Impact Factor 4.253, Q1

 

8) C. Carfagna, R. Galarini, A. Musco, R. Santi

"Reaction of allyl acetates and ketene silyl acetals catalyzed by Palladium (0) complexes part II. Cyclopropanation vs. allylic alkylation"

J. Mol. Catal. 1992, 72, 19-27

Impact Factor 2.947

 

9) C. Carfagna, R. Galarini, K. Linn, J.A. López, C. Mealli, A. Musco

"Nucleophilic Attack at the Central Allyl Carbon atom in [( 3 -allyl)ML2]+Complexes (M = Pd, Pt). Experimental Facts and New Theoretical Insights"

Organometallics 1993, 12, 3019-3028

Impact Factor 4.253, Q1

 

10) C. Carfagna, M. Green, K.R. Nagle, D.J. Williams, C.M. Woolhouse

"Reactions of co-ordinated Ligands. Part 56. Synthesis and Reactivity of [Mo{ h3 , h3 -CH(Me)C(Me)CHCHC(Me)CH2}(CO)( h -C5H5)][BF4] formed by Coupling of But-2-yne and Isoprene Ligands; Reactions of [Mo( h2 -C2H4)( h 2 -MeC2Me)(CO)( h -C5H5)][BF4]"

J. Chem. Soc. Dalton Trans. 1993, 1761-1770

Impact Factor 4.097, Q1

 

11) C.Carfagna, M. Green, M.F. Mahon, S. Rumble, C.M. Woolhouse

"Reactions of Three-electron , h2 - Prop-2-ynyl Ligands formed by deprotonation of Four-electron h2 -Alkyne Molybdenum complexes"

J. Chem. Soc. Chem. Commun. 1993, 879-881

Impact Factor 6.718, Q1

 

12) S. Bartolini, C. Carfagna, A. Musco

"Enantioselective isotactic alternating copolymerization of styrene and 4-metylstyrene with carbon monoxide catalyzed by a cationic bioxazoline Pd(II) complex"

Macromol. Rapid Commun. 1995, 16, 9-14

Impact Factor 4.608, Q1

 

13) C. Carfagna, R. J. Deeth, M. Green, M. F. Mahon, J.M. McInnes, S. Pellegrini, C.B. Woolhouse

"Deprotonation of 2 (4e)-Bonded Alkynes as a Pathway to , 2 (3e)-Prop-2-ynyl, 5 -Pentadienyl and 4 -trans-1,3-Diene Substituted Molybdenum Complexes"

J. Chem. Soc. Dalton Trans. 1995, 3975-3985

Impact Factor 3.023, Q1

 

14) C.Carfagna, N. Carr, R.J. Deeth, S.J. Dossett, M. Green, M.F. Mahon, C.Vaughan

"Synthesis and reactivity of 2 (4e)-alkyne and 2 (3e)-vinyl complexes of rhenium".

J.Chem Soc.Dalton Trans. 1996, 415-430

Impact Factor 4.097, Q1

 

15) P. Lorente, C. Carfagna, M. Etienne, B. Donnadieu

"Alkyne and Nitrile as 2 (3e) Ligands in Tris(pyrazolyl)borato niobium(I) Complexes. Synthesis, Structure, and Coupling Reaction".

Organometallics 1996, 15, 1090-1092

Impact Factor 4,253, Q1

 

16) C. Carfagna, M. Green, M.F. Mahon, J.M. McInnes, S.J. Rumble, C.M. Woolhouse

"Molybdenum-mediated cocyclisation reactions involving prop-2-ynyl, alkyne and carbon monoxide ligands".

J. Chem. Soc. Dalton Trans. 1996, 16, 3379-3385

Impact Factor 4.097, Q1

 

17) C. Carfagna, M. Formica, G. Gatti, A. Musco, A. Pierleoni

"Quantitative formation of the intermediate of alkene insertion in the copolymerization of p-methylstyrene and carbon monoxide catalyzed by [(PriDAB)Pd(Me)(NCMe)]+BAr4-."

J. Chem. Soc. Chem. Commun. 1998, 1113-1114

Impact Factor 6.718, Q1

 

18) M. Etienne, C. Carfagna, P. Lorente, R. Mathieu, D. de Montauzon

"Structure and Reactivity of h 2 (3e)-Nitrile and h 2 (3e)-Alkyne Complexes of Niobium"

Organometallics 1999, 18, 3075-3086

Impact Factor 4.253, Q1

 

19) A. Macchioni, G. Bellachioma, G. Cardaci, M. Travaglia, C. Zuccaccia, B. Milani, G. Corso, E. Zangrando, G. Mestroni, C. Carfagna, M. Formica

"Counterion Effect on CO/Styrene Copolymerization Catalyzed by Cationic Palladium(II) Organometallic Complexes: An Interionic Structural and Dynamic Investigation Based on NMR Spectroscopy"

Organometallics 1999, 18, 3061-3069

Impact Factor 4.253, Q1

 

20) B. Milani, G. Corso, G. Mestroni, C. Carfagna, M. Formica, R. Seraglia

"Highly Efficient Catalytic System for the CO/Styrene Copolymerization toward the Stabilization of the Active Species"

Organometallics 2000, 19, 3435-3441

Impact Factor 4.253, Q1

 

21) C. Carfagna, G. Gatti, D. Martini, C. Pettinari

"Syndiotactic CO/Styrene Copolymerization Catalyzed by a -Diimine Pd(II) Complexes: Regio- and Stereochemical Control"

Organometallics 2001, 20, 2175-2182

Impact Factor 4.253, Q1

 

22) G. Bellachioma, B. Binotti, G. Cardaci, C. Carfagna, A. Macchioni, S. Sabatini, C. Zuccaccia

"Solution Structure Investigations of Olefin Pd(II) and Pt(II) Complex Ion Pairs Bearing a -Diimine Ligands by 19F, 1H-HOESY NMR"

Inorg. Chim. Acta 2002, 330, 44-51

Impact Factor 2.041, Q2

 

23) A. Macchioni, C. Zuccaccia, B. Binotti, C. Carfagna, E. Foresti, P. Sabatino

"Cationic Olefin Pd(II) Complexes Bearing a -Iminoketone N,O-Ligands: Unprecedented Isomerization of the Methoxycyclooctenyl Ligand"

Inorg. Chem. Commun. 2002, 5, 319-322

Impact Factor 2.062, Q2

 

24) B. Milani, A. Scarel, G. Mestroni, S. Gladiali, R. Taras, C. Carfagna, L. Mosca

"Very Stable Palladium(II)-(N-N) Catalysts for the Synthesis of High Molecular Weight CO/Styrene Polyketones"

Organometallics 2002, 21, 1323-1325

Impact Factor 4.253, Q1

 

25) B. Binotti, C. Carfagna, G. Gatti, D. Martini, L. Mosca, C. Pettinari

"Mechanistic Aspects of Isotactic CO/Styrene Copolymerization Catalyzed by Oxazoline Palladium(II) Complexes"

Organometallics 2003, 22, 1115-1123

Impact Factor 4.253, Q1

 

26) B. Milani, A. Scarel, E. Zangrando, G. Mestroni, C. Carfagna, B. Binotti

"Cationic palladium complexes with mono- and bidentate nitrogen-donor ligands: synthesis, characterization and reactivity in CO/styrene copolymerization reaction"

Inorg. Chim. Acta 2003, 350, 592-602

Impact Factor 2.041, Q2

 

27) B. Milani; A. Scarel; J. Durand; G. Mestroni; R. Seraglia; C. Carfagna; B. Binotti

"MALDI-TOF Mass Spectrometry in the Study of CO/Aromatic Olefins Terpolymers"

Macromolecules 2003, 36, 6295-6297

Impact Factor 5.927, Q1

 

28) C. Carfagna, G. Gatti; L. Mosca, P. Paoli, A. Guerri

"Synthesis of a Novel a -Diimine Palladium(II) Complex Bearing an h 3 -Allyl g -Lactone Ligand, a Key Intermediate in Alkyne Cyclocarbonylation Processes"

Organometallics 2003, 22, 3967-3970

Impact Factor 4.253, Q1

 

29) E. Zangrando, M. Trani, E. Stabon, C. Carfagna, B. Milani, G. Mestroni

"Synthesis and Molecular Structures of Nickel(II) and Cobalt(III) Complexes with 2-(arylimino)-3-(hydroxyimino)butane"

Eur. J. Inorg. Chem. 2003, 14, 2683-2692

Impact Factor 2.965, Q1

 

30) B.Binotti, C. Carfagna, E. Foresti, A. Macchioni, P. Sabatino, C. Zuccaccia, D. Zuccaccia

"Cationic Olefin Pd(II) Complexes Bearing  a -Iminoketone N,O-Ligands: Synthesis, Intramolecular and Interionic Characterization and Reactivity with Olefins and Alkynes"

J. Organomet. Chem. 2004, 689, 647-661

Impact Factor 2.302, Q2

 

31) A. Scarel, B. Milani, E. Zangrando, M. Stener, S. Furlan, G. Fronzoni, G. Mestroni, S. Gladiali, C. Carfagna, L. Mosca

"Palladium Complexes with 3-Alkyl-Substituted-1,10-Phenanthrolines: Effect of the Remote Alkyl Substituent on the CO/Olefin Copolymerization Reactions"

Organometallics 2004, 23, 5593-5605

Impact Factor 4.253, Q1

 

32) B. Binotti, C. Carfagna, C. Zuccaccia, A. Macchioni

"From Atactic to Isotactic CO/p-Methylstyrene Copolymer by Proper Modifications of Pd(II) Catalysts Bearing Achiral a -Diimines"

Chem. Commun. 2005, 92-94

Impact Factor 6.718, Q1

 

33) C. Carfagna, G. Gatti, L. Mosca, P. Paoli, A. Guerri

"Stereocontrol in Alkyne Cyclocarbonylation Reactions promoted by a Bioxazoline Palladium(II) Complex"

Chem. Eur. J. 2005, 11, 3268-3278

Impact Factor 5.696, Q1

 

34) A. Scarel, J. Durand, D. Franchi, E. Zangrando, G. Mestroni, C. Carfagna, L. Mosca, R. Seraglia, G. Consiglio, B. Milani

" Mono- and Dinuclear Bioxazoline-Palladium Complexes for the Stereocontrolled Synthesis of CO/styrene Polyketones"

Chem. Eur. J. 2005, 11, 6014-6023

Impact Factor 5.696, Q1

 

35) A. Scarel, J. Durand, D. Franchi,  E. Zangrando, G. Mestroni, B. Milani, S. Gladiali, C. Carfagna, B. Binotti, S. Bronco, T. Gragnoli

"Trifluoroethanol: Key Solvent for Palladium-Catalyzed Polymerization Reactions"

J. Organomet. Chem. 2005, 690, 2106-2120

Impact Factor 2.302, Q2

 

36)S. D. Bergman, I. Goldberg, C. Carfagna, L. Mosca, M. Kol, B. Milani 

“Palladium Complexes Containing Large Fused Aromatic N-N Ligands as Efficient Catalysts for the CO/Styrene Copolymerization “

Organometallics  2006,  25(26),  6014-6018

Impact Factor 4.253, Q1

 

37) J. Durand, E. Zangrando, M. Stener, G. Fronzoni, C. Carfagna, B. Binotti, P. C. J. Kamer, C. Mueller, M. Caporali, P. W. N. M. van Leeuwen, D. Vogt, B. Milani

“Long-lived palladium catalysts for CO/vinyl arene polyketones synthesis: a solution to deactivation problems”

Chem. Eur. J.   2006,  12(29),  7639-7651

Impact Factor 5.696, Q1

 

38) J. Durand, A. Scarel, B. Milani, R. Seraglia, S. Gladiali, C. Carfagna, B. Binotti      

“Palladium-promoted carbon monoxide/ethylene/styrene terpolymerization reaction: throwing light on the different reactivity of the two alkenes”

Helvetica Chimica Acta   2006,  89(8),  1752-1771

Impact Factor 1.394, Q3

 

39) C. Carfagna, G. Gatti, L. Mosca, P. Paoli, A Guerri

“Insertion reactions of 1,2-disubstituted olefins with an a -diimine palladium(II) complex”

Helvetica Chimica Acta   2006,  89(8),  1660-1671

Impact Factor 1.394, Q3

 

40) C. Zuccaccia, G. Bellachioma, G. Cardaci, A. Macchioni, B. Binotti, C. Carfagna

“Synthesis, interionic structure, and reactivity toward CO and p-methylstyrene of palladacyclic compounds bearing a -diimine ligands”

Helvetica Chimica Acta   2006,  89(8),  1524-1546

Impact Factor 1.394, Q3

 

41) A. Schaetz, A. Scarel, E. Zangrando, L. Mosca, C. Carfagna, A. Gissibl, B. Milani, O. Reiser   

“High Stereocontrol and Efficiency in CO/Styrene Polyketone Synthesis Promoted by Azabis(oxazoline)-Palladium Complexes”

Organometallics  2006,  25(17) ,  4065-4068

Impact Factor 4.253, Q1

 

42) B. Binotti, G. Bellachioma, G. Cardaci, C. Carfagna, C. Zuccaccia, A.  Macchioni

“The effect of counterion/ligand interplay on the activity and stereoselectivity of palladium(II)-diimine catalysts for CO/p-methylstyrene copolymerization”

Chem. Eur. J. 2007,  13(5),  1570-1582

Impact Factor 5.696, Q1

 

43) C. Carfagna, G. Gatti, L. Mosca, A. Passeri, P. Paoli, A. Guerri

“Stereocontrol mechanism in CO/p-methylstyrene copolymerisation catalysed by aryl- a -diimine Pd(II) complexes”

Chem. Commun. 2007, 43,  4540-4542

Impact Factor 6.718, Q1

 

44) J. Durand, E. Zangrando, C. Carfagna, B. Milani

“New atropisomeric N-N ligands for CO/vinyl arene copolymerization reaction”

Dalton Trans. 2008, 16,  2171-2182

Impact Factor 4.097, Q1

 

45) A. Scarel, M.R. Axet, F. Amoroso, F. Ragaini, C.J. Elsevier, A. Holuigue, C. Carfagna, L. Mosca, B. Milani

“Subtle balance of steric and electronic effects for the synthesis of atactic polyketones catalyzed by Pd complexes with meta-substituted aryl-BIAN ligands”

Organometallics 2008, 27,  1486-1494

Impact Factor 4.253, Q1

 

46) C. Carfagna, G. Gatti, P. Paola, P.Rossi

"Mechanism for stereoblock isotactic CO/styrene copolymerization promoted by aryl a-diimine Pd(II) catalysts: a DFT study"

Organometallics  2009, 28, 3212-3217

Impact Factor 4.253, Q1

 

47) M. R. Axet, F. Amoroso, G. Bottari, A. D'Amora, E. Zangrado, F. Faraone, D. Drommi, M.Saporita, C.Carfagna, P.Natanti, R. Seraglia, B. Milani

"Application of chiral amine-imine ligands in palladium-catalyzed polyketone synthesis: effect of ligand backbone on the polymer stereochemistry"

Organometallics  2009, 28, 4464-4474

Impact Factor 4.253, Q1

 

48) C. Carfagna, G. Gatti, L. Mosca, P. Natanti, P. Paoli, P. Rossi, B. Gabriele, G. Salerno

“Carbonylation of styrenes catalyzed by bioxazoline Pd(II) complexes: mechanism of enantioselectivity”

Dalton Transactions  2011, 40(25), 6792-6801

Impact Factor 4.097, Q1

 

49) B. Gabriele, R. Mancuso, E. Lupinacci, L.Veltri, G. Salerno, C. Carfagna

“ Synthesis of Benzothiophene Derivatives by Pd-Catalyzed or Radical-Promoted Heterocyclodehydration of 1-(2-Mercaptophenyl)-2-yn-1-ols ”

J. Org. Chem. 2011, 76, 8277- 8286

Impact Factor 4.638, Q1

 

50) F. Amoroso, E. Zangrando, C. Carfagna, C. Müller, D. Vogt, M. Hagar, F. Ragaini, B. Milani

“Catalyst activity or stability: the dilemma in Pd-catalyzed polyketone synthesis”

Dalton Trans. 2013, 42, 14583-14602

Impact Factor 4.097, Q1

 

51) C. Carfagna, G. Gatti, P. Paoli, B. Binotti, F. Fini, A. Passeri, P. Rossi, B. Gabriele

"New aryl a-diimine Palladium(II) catalysts in stereocontrolled CO/vinyl arene copolymerization"

Organometallics  2014, 33, 129-144

Impact Factor 4.253, Q1

52) V. Rosar, A. Meduri, T. Montini, F. Fini, C. Carfagna,P. Fornasiero, G. Balducci,

E. Zangrando, B. Milani

“Analogies and differences in palladium-catalyzed CO/styrene and ethylene/methyl acrylate copolymerization reactions”

ChemCatChem 2014, 6, 2403-2418

Impact Factor 5.044, Q1

53) B. Gabriele, L. Veltri, R. Mancuso, C. Carfagna

“Cascade Reactions: A Multicomponent Approach to Functionalized Indane Derivatives by a Tandem Palladium-Catalyzed Carbamoylation / Carbocylization Process”

Adv. Synth. and Catal. 2014, 356, 2547-2558

Impact Factor 5.542, Q1

54) F. Fini, M. Beltrani, R. Mancuso, B. Gabriele, C. Carfagna

“Selective Aryl a-Diimmine/Palladium-Catalyzed Bis-Alkoxycarbonylation of Olefins for the Synthesis of Substituted Succinic Diesters”

Adv. Synth. and Catal. 2014 accepted for publication

Impact Factor 5.542, Q1

BREVETTI INDUSTRIALI

1) A. Musco, G. Terzoni, C. Pavisic, C. Carfagna

"Procedimento perfezionato per la riduzione di composti organici mediante l'impiego diidruro di magnesio"

Brev. Ital. depositato il 23/03/88, n° 19903N88.

2) C. Carfagna, A. Musco, G. Sallese, R. Santi

"Processo per la preparazione di esteri degli acidi 2-aril-alcanoici".

Brev. Ital. depositato il 5/10/1989, n° B-707-06.